Unusual hydrothermal synthesis of a heteroaromatic macrocyclic complex

Burkholder, E. and Heirtzler, F. and Orian, L. and Ouellette, W. and Zubieta, J. (2008) Unusual hydrothermal synthesis of a heteroaromatic macrocyclic complex. Polyhedron, 27 (18). pp. 3700-3702. ISSN 0277-5387. (The full text of this publication is not available from this repository)

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Official URL
http://dx.doi.org/10.1016/j.poly.2008.09.007

Abstract

Hydrothermal treatment of 2,3-bis(2',6"-bipyridyl)quinoxaline, molybdenum trioxide, cupric acetate and water unexpectedly forms the Cu(II) complex of a planar, macrocyclic 2-acyl-6,2'-bipyridyl dimer, imbedded within a copper benzotrizolate-octamolybtate matrix. X-ray crystallographic characterization of this material. and scalar relativistic ZORA DFT modeling of the complex dication are presented.

Item Type: Article
Uncontrolled keywords: Macrocycle Structure Copper Hydrothermal Molybdenum
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Science Technology and Medical Studies > School of Physical Sciences
Depositing User: Suzanne Duffy
Date Deposited: 04 Feb 2009 12:54
Last Modified: 04 Feb 2009 12:54
Resource URI: http://kar.kent.ac.uk/id/eprint/14853 (The current URI for this page, for reference purposes)
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