Burkholder, E. and Heirtzler, F. and Orian, L. and Ouellette, W. and Zubieta, J. (2008) Unusual hydrothermal synthesis of a heteroaromatic macrocyclic complex. Polyhedron, 27 (18). pp. 3700-3702. ISSN 0277-5387.
| The full text of this publication is not available from this repository. (Contact us about this Publication) | |
| Official URL http://dx.doi.org/10.1016/j.poly.2008.09.007 |
Abstract
Hydrothermal treatment of 2,3-bis(2',6"-bipyridyl)quinoxaline, molybdenum trioxide, cupric acetate and water unexpectedly forms the Cu(II) complex of a planar, macrocyclic 2-acyl-6,2'-bipyridyl dimer, imbedded within a copper benzotrizolate-octamolybtate matrix. X-ray crystallographic characterization of this material. and scalar relativistic ZORA DFT modeling of the complex dication are presented.
| Item Type: | Article |
|---|---|
| Uncontrolled keywords: | Macrocycle Structure Copper Hydrothermal Molybdenum |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculties > Science Technology and Medical Studies > School of Physical Sciences |
| Depositing User: | Suzanne Duffy |
| Date Deposited: | 04 Feb 2009 12:54 |
| Last Modified: | 04 Feb 2009 12:54 |
| Resource URI: | http://kar.kent.ac.uk/id/eprint/14853 (The current URI for this page, for reference purposes) |
- Depositors only (login required):
