Structural characterization of water and ice in mesoporous SBA-15 silicas: II. The 'almost-filled' case for 86 angstrom pore diameter

Seyed-Yazdi, J. and Farman, H. and Dore, J.C. and Webber, J.B.W. and Findenegg, G.H. and Hansen, T. (2008) Structural characterization of water and ice in mesoporous SBA-15 silicas: II. The 'almost-filled' case for 86 angstrom pore diameter. Journal of Physics-~Condensed Matter, 20 (20). ISSN 0953-8984 . (Access to this publication is restricted)

PDF (Published Paper)
Restricted to Repository staff only
Contact us about this Publication Download (636kB)
[img]
PDF (Latex output) - Accepted Version
Available under License Creative Commons Attribution.
Download (500kB)
[img]
Preview
Official URL
http://dx.doi.org/10.1088/0953-8984/20/20/205107

Abstract

Neutron diffraction measurements for D2O in SBA-15 silica of pore diameter 86 angstrom have been made in a temperature range from 300 to 100 K. The pore-filling factor for the liquid phase is 0.95, resulting in an `almost-filled' sample. The nucleation and transformation of the ice phase were determined for cooling and warming cycles at two different rates. The primary nucleation event at 258 K leads to a defective form of ice-I with predominantly cubic ice features. For temperatures below the main nucleation event, the data indicate the formation of an interfacial layer of disordered water/ice that varies with temperature and is reversible. The main diffraction peak for the water phase shows similar features to those observed in earlier studies, indicating enhanced hydrogen bonding and network correlations for the confined phase as the temperature is decreased. A detailed profile analysis of the triplet peak is presented in the accompanying paper (Seyed-Yazdi et al 2008 J. Phys.: Condens. Matter 20 205108).

Item Type: Article
Additional information: 11th International Conference on Magnetic Fluids Kosice, Slovakia, July 23-27, 2007
Subjects: Q Science > QC Physics
Divisions: Faculties > Science Technology and Medical Studies > School of Physical Sciences > Functional Materials Group
Depositing User: J.B.W. Webber
Date Deposited: 26 Mar 2009 09:55
Last Modified: 06 Sep 2011 01:07
Resource URI: http://kar.kent.ac.uk/id/eprint/13469 (The current URI for this page, for reference purposes)
  • Depositors only (login required):

Downloads

Downloads per month over past year