Dore, J.C. and Webber, J.B.W. and Hartl, M. and Behrens, P. and Hansen, T. (2002) Neutron diffraction studies of structural phase transformations for water-ice in confined geometry. Phsica A- statistical Mechanicsand its Applications, 314 (1-4). pp. 501-507. ISSN 0378-4371 . (Access to this publication is restricted)
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Neutron diffraction measurements have been made for D2O water in the confined geometry of various mesoporous silicas over a wide temperature range. The data have been taken for cooling and heating runs incorporating the nucleation and melting of the crystalline phases and the super-cooled liquid phase. The crystalline forms and the temperatures at which they change are shown to be strongly dependent on the pore size and type of silica used as the confining medium and relate to the phase relationship between hexagonal ice [I-h] and cubic ice [I-c].
|Additional information:||Meeting on Horizons in Complex Systems, MESSINA, ITALY, DEC, 2001|
|Uncontrolled keywords:||water; ice; mesoporous silica; MCM-silica; phase transformation; neutron diffraction|
|Subjects:||Q Science > QC Physics|
|Divisions:||Faculties > Science Technology and Medical Studies > School of Physical Sciences > Functional Materials Group|
|Depositing User:||J.B.W. Webber|
|Date Deposited:||11 Mar 2009 23:01|
|Last Modified:||04 May 2012 14:39|
|Resource URI:||http://kar.kent.ac.uk/id/eprint/13456 (The current URI for this page, for reference purposes)|