Spatially resolved pore size distributions by NMR

Webber, J.B.W. and Strange, JH (1997) Spatially resolved pore size distributions by NMR. MEASUREMENT SCIENCE & TECHNOLOGY, 8 (5). pp. 555-561. ISSN 0957-0233.

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Official URL
http://dx.doi.org/10.1088/0957-0233/8/5/015

Abstract

We have developed a novel method of determining median pore size and pore size distributions as a function of spatial position inside a porous sample. Pore sizes have been measured with one-, two- and three-dimensional spatial resolutions, using nuclear magnetic resonance (NMR) cryoporometry in conjunction with magnetic resonance imaging techniques. NMR cryoporometry is a method of measuring pore sizes and pore size distributions in the range of less than 40 Angstrom to over 2000 Angstrom pore diameter, by the technique of freezing a liquid in the pores and measuring the melting temperature by NMR. Since the melting point is depressed for crystals of small size, the melting point depression gives a measurement of pore size.

Item Type: Article
Subjects: Q Science > QC Physics
Divisions: Faculties > Science Technology and Medical Studies > School of Physical Sciences > Functional Materials Group
Depositing User: J.B.W. Webber
Date Deposited: 20 Jul 2009 23:04
Last Modified: 22 Dec 2011 22:32
Resource URI: http://kar.kent.ac.uk/id/eprint/13450 (The current URI for this page, for reference purposes)
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