Jordan, P.M. and Cheung, K.M. and Sharma, R.P. and Warren, M.J. (1993) 5-Amino-6-Hydroxy-3,4,5,6-Tetrahydropyran-2-One (Hat) - a Stable, Cyclic Form of Glutamate 1-Semialdehyde, the Natural Precursor for Tetrapyrroles. Tetrahedron Letters, 34 (7). pp. 1177-1180. ISSN 0040-4039 .
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Glutamate 1-semialdehyde is shown to exist in a cyclic form, 5-amino-6-hydroxy-3,4,5,6-tetrahydropyran-2-one (HAT), which explains its unexpectedly high stability for an alpha-aminoaldehyde. It is proposed that the cyclic form is the actual intermediate in the biosynthesis of tetrapyrroles.
|Uncontrolled keywords:||delta-aminolevulinate greening barley biosynthesis|
|Divisions:||Faculties > Science Technology and Medical Studies > School of Biosciences|
|Depositing User:||Martin Warren|
|Date Deposited:||21 Oct 2009 08:26|
|Last Modified:||14 Jan 2010 14:42|
|Resource URI:||http://kar.kent.ac.uk/id/eprint/11112 (The current URI for this page, for reference purposes)|
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